Interfacial structure and structural forces in mixtures of ionic liquid with a polar solvent
نویسندگان
چکیده
منابع مشابه
A structural investigation of ionic liquid mixtures.
The structures of mixtures of ionic liquids (ILs) featuring a common 1-butyl-3-methylimidazolium ([C4C1im](+)) cation but different anions have been investigated both experimentally and computationally. (1)H and (13)C NMR of the ILs and their mixtures has been performed both on the undiluted liquids and those diluted by CD2Cl2. These experiments have been complemented by quantum chemical densit...
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High-pressure infrared measurements were carried out to observe the microscopic structures of two imidazolium-based ionic liquids, i.e., 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide [EMI(+)(CF(3)SO(2))(2)N(-), EMI(+)TFSA(-)] and 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide [EMI(+)(FSO(2))(2)N(-), EMI(+)FSA(-)]. The results obtained at ambient pressure indicate that the ...
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15 صفحه اولLaser photolysis study of anthraquinone in binary mixtures of ionic liquid [bmim][PF6] and organic solvent
Photochemical properties of the ionic liquid (RTIL) 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] and its binary mixed solutions with organic solvent (DMF and MeCN) were investigated by laser photolysis at an excitation wavelength of 355 nm, using anthraquinone (AQ) as a probe molecule. It was indicated that the triplet excited state of AQ (AQ*) can abstract hydrogen from [bmim][P...
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ژورنال
عنوان ژورنال: Faraday Discussions
سال: 2018
ISSN: 1359-6640,1364-5498
DOI: 10.1039/c7fd00168a